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My switch OLED got a scratch across the shatter film while I was waiting for my screen protectors to be delivered. Is it safe to remove the shutter film and just put on a screen protector? Is there a replacement shatter film anywhere that I could get? Or am I just SOL?

I am confused on what you are talking about exactly. Are you meaning the Glass covering the OLED Screen if you are removing it is not a good idea it will expose the OLED and you could damage the OLED in the process as its fused to the glass.

You should be referring to this one: Cover adhesive film for nintendo switch oled screen surface However, this replacement requires a certain skill, not a simple replacement of the surface.